Method for preparing hydroperoxides by oxygenation

C - Chemistry – Metallurgy – 07 – C

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C07C 409/10 (2006.01) C07C 49/08 (2006.01) C07C 407/00 (2006.01)

Patent

CA 2255484

Aryldialkylmethanes such as cumene are converted to the corresponding hydroperoxides by reaction with oxygen in the presence of a promoter which may be an alkali metal borate such as borax, an alkali metal salt of a polymer such as an acrylic polymer or an alkaline reagent in combination with a specific proportion of added water or water of hydration, also exemplified by borax. High yields of the hydroperoxide are obtained particularly when the promoter includes water.

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