Method for preparing low free formaldehyde...

C - Chemistry – Metallurgy – 07 – D

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C07D 233/74 (2006.01) A01N 43/50 (2006.01) B27K 3/00 (2006.01) C07D 233/78 (2006.01) C09D 5/14 (2006.01) C11D 3/48 (2006.01) A61K 7/00 (1990.01)

Patent

CA 2093045

Compositions of dimethyloldimethylhydantoin, monomethyloldimethylhydantoin, and dimethylhydantoin having less than 0.1% by weight of free formaldehyde based upon 100% by weight of total composition; and wherein the weight ratio of di- methyloldimethylhydantoin to monomethyloldimethylhydantoin ranges from about 1:1.25 to about 3.5:1, are provided. These compositions may be prepared (1) by reacting dimethylhydantoin and a formaldehyde-containing source wherein the molar ratio of formal- dehyde to dimethylhydantoin ranges from about 1.2:1 to about 1.55:1 or (2) by admixing (a) from about 80 to about 90% by weight of an aqueous solution of methyloldimethylhydantoin having greater than about 0.1% by weight of free formaldehyde with (b) about 20 to about 10% by weight of dimethylhydantoin based upon 100% weight of aqueous dimethyloldimethylhydantoin solution and dimethylhydantoin combined. The compositions are useful as, inter alia, antimicrobial agents useful to extend the shelf life of various preparations susceptible to microbial growth.

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