Method for producing 3-alkylphenols and 1,3- dihydroxybenzene

C - Chemistry – Metallurgy – 07 – C

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260/621.5, 260/6

C07C 39/02 (2006.01)

Patent

CA 1139787

ABSTRACT This invention describes a four-step process for preparing 3-alkylphenols and 1,3-dihydroxybenzene comprising the alkylation of benzene or a monoalkyl- benzene followed by the selectove reaction of the 1,4- isomer of the alkylation product in the presence of a specified type of shape selective zeolite to obtain the 1,3-isomer in excess of equilibrium. Subsequent oxidation and acid catalyzed rearrangement results in a significant yeild of 1,3-dihydroxybenzene or 3-alkyl- phenol. F-COO?(0026 ? ?27)

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