Method for producing alcohol/ketone mixtures

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 45/53 (2006.01) B01J 31/16 (2006.01) B01J 31/18 (2006.01) C07C 29/132 (2006.01) C07C 35/08 (2006.01) C07C 49/403 (2006.01) C07C 409/14 (2006.01)

Patent

CA 2394259

The invention relates to a method for producing a mixture of alcohols/ketones by decomposing an alkyl hydroperoxide, particularly to a method for producing a cyclohexanol/cyclohexanone by decomposing cyclohexyl hydroperoxide in the presence of a heterogeneous catalyst. According to the invention, the reaction is carried out in the presence of a heterogeneous catalyst containing an organometallic segment fixed on the surface of a porous solid compound such as silicon. The organometallic segment ca be formula (I).

L'invention concerne un procédé de préparation d'un mélange alcools/cétones par décomposition d'un hydropéroxyde d'alkyle. Elle se rapporte plus particulièrement à la préparation d'un mélange cyclohexanol/cyclohexanone par décomposition d'hydropéroxyde de cyclohexyle en présence d'une catalyse hétérogène. Selon l'invention, la réaction est réalisée en présence d'un catalyseur hétérogène comprenant un segment organométallique fixé sur la surface d'un composé solide poreux comme de la silice. Le segment organométallique peut correspondre à la formule générale (I).

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