Method for producing fluorinated organic compounds

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 17/23 (2006.01) C07C 17/00 (2006.01) C07C 17/25 (2006.01) C07C 17/278 (2006.01) C07C 19/10 (2006.01) C07C 21/18 (2006.01)

Patent

CA 2628446

Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m >= 0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).

L'invention concerne un procédé de production de composés organiques fluorés comprenant des hydrofluoropropènes, ce procédé consistant, de préférence, à convertir au moins un composé de formule (I): CF3CFnCHmXa-m, en au moins un composé de formule (II) CF3CZCHZ. Chaque X représente, indépendamment, Cl, F, I ou Br; chaque Z représente, indépendamment, H ou F; n représente 1 ou 2; m représente 1, 2 ou 3, à condition que, lorsque n représente 1, m représente 1 ou 2; a représente 2 ou 3 et a-m = 0. Certains modes de réalisation consistent à faire réagir l'oléfine C2 fluorée, telle que le tétrafluoroéthylène, avec un agent d'addition C1 dans des conditions efficaces pour produire un composé de formule (I).

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