Method for producing high activity photocatalyst and method...

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B01J 35/02 (2006.01) B01J 27/04 (2006.01) B01J 35/00 (2006.01) B01J 37/12 (2006.01) C01B 3/04 (2006.01) C01B 17/05 (2006.01) C01B 17/06 (2006.01) C01G 9/08 (2006.01)

Patent

CA 2421178

A high activity catalyst is obtained by oxidizing and modifying the surface of zinc sulfide by hydrogen peroxide. An oxidation treatment is carried out in basic aqueous solution. The high activity photocatalyst is added to the basic aqueous solution in which hydrogen sulfide is dissolved to recover hydrogen and sulfur under low energy. Thus, the inexpensive high activity photocatalyst having a high catalytic activity and a long duration of life is realized and hydrogen gas is efficiently generated under little energy.

L'invention concerne un procédé de préparation d'un photocatalyseur hautement actif, consistant à soumettre la surface d'un produit de sulfure de zinc à un traitement oxydant avec du peroxyde d'hydrogène afin de le modifier. Le traitement oxydant est, de préférence, réalisé dans une solution de base aqueuse. L'invention concerne également un procédé de traitement de sulfure d'hydrogène, consistant à ajouter le photocatalyseur hautement actif à une solution de base aqueuse contenant du sulfure d'hydrogène afin de récupérer l'hydrogène et le soufre. Ledit photocatalyseur est un nouveau catalyseur à activité élevée, peu coûteux et de longue durée de vie, pouvant donc être utilisé pour générer de l'hydrogène du sulfure d'hydrogène de manière efficace et avec une faible consommation d'énergie.

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