Method for producing hydrocarbons and oxygen-containing...

C - Chemistry – Metallurgy – 12 – P

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C12P 7/06 (2006.01)

Patent

CA 2541899

A method which can be used in fermenting carbohydrate substrates of plant origin for producing C1-C5 alcohols, and for synthesis of higher alcohols, and other oxygen-containing compounds. Since C6 and higher alcohols are not obtainable by a direct biochemical route, it is proposed to synthesize these using known chemical reactions, wherein the raw material for synthesis is biogas and lower C2-C5 alcohols obtained by the inventive method wherein the amino acids leucine, isoleucine, and valine, or a mixture thereof, optionally obtained from yeast autolysate, is used as a biocatalyst at the stage of fermentation. It is also proposed to use wasters of C2-C5 alcohols production for obtaining biogas. The method offers a solution to the following problems: to considerably increase the yield of C2-C5 alcohols in fermentation of carbohydrate substrates; to increase by 1.5-2.0 times the productivity of the fermentation in terms of C2-C5 alcohols production; to utilize the protein- containing waste for C2-C5 alcohols production, to reach highest efficiency of biomass utilization in producing higher oxygen-containing compounds and hydrocarbons.

L'invention concerne un procédé qui peut servir à fermenter des substrats à base d'hydrates de carbone d'origine végétale afin de produire des alcools C¿1?-C¿5? et de synthétiser des alcools supérieurs et d'autres composés contenant de l'oxygène. Etant donné que C¿6? et les alcools supérieurs ne peuvent être obtenus par une voie biochimique directe, il est proposé de synthétiser ces réactions chimiques connues, en utilisant, comme matériau brut pour la synthèse, un biogaz et les alcools inférieurs C¿2?-C¿5? obtenus au moyen du procédé selon l'invention, les acides aminés leucine, isoleucine et valine ou un mélange de ces derniers, éventuellement obtenus à partir d'un autolysat de levure, servant de biocatalyseur à l'étape de fermentation. Il est également proposé d'utiliser les rebuts de la production d'alcools C¿2?-C¿5? pour obtenir un biogaz. Le procédé selon l'invention permet d'augmenter considérablement le rendement d'alcools C¿2?-C¿5? dans la fermentation de substrats d'hydrates de carbone, d'augmenter de 1,5 à 2,0 fois la productivité de la fermentation en termes de production d'alcools C¿2?-C¿5?, d'utiliser les déchets contenant des protéines pour la production d'alcools C¿2?-C¿5?, d'atteindre la plus haute efficacité d'utilisation de la biomasse lors de la production de composés supérieurs contenant de l'oxygène et d'hydrocarbures.

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