C - Chemistry – Metallurgy – 07 – F
Patent
C - Chemistry, Metallurgy
07
F
C07F 9/38 (2006.01)
Patent
CA 2451507
The invention relates to a method for producing N-phosphonomethylglycine from an aqueous mixture containing N-phosphonomethylglycine, ammonium halogenides and alkali halides or earth alkali halides and optionally, organic impurities in a dissolved form. According to the invention, (a) the pH-value of the mixture is regulated to a value of 2 - 8, (b) the mixture is separated by means of a selective nano-filtration membrane, to obtain a retentate rich in N- phosphonomethylglycine and poor in halogenides and a permeate rich in halogenides and poor in N-phosphonomethylglycine and (c) the N- phosphonmethylglycine is prepared from the retentate. The inventive method enables the production of N-phosphonomethylglycine by simultaneously separating the halogenide salts thereof.
L'invention concerne un procédé pour la production de N-phosphonométhylglycine à partir d'un mélange aqueux qui contient de la N-phosphonométhylglycine, des halogénures d'ammonium ainsi que des halogénures alcalins ou alcalino-terreux et, éventuellement, des impuretés organiques sous forme dissoute. Selon l'invention, (a) on règle la valeur du pH du mélange à une valeur comprise entre 2 et 8, (b) on sépare le mélange au moyen d'une membrane de nanofiltration sélective, obtenant ainsi un rétentat plus riche en N-phosphonométhylglycine et plus pauvre en halogénures et un perméat plus riche en halogénures et plus pauvre en N-phosphonométhylglycine, et (c) on prépare la N-phosphonométhylglycine à partir du rétentat. Le procédé selon l'invention permet la production de N-phosphonométhylglycine avec séparation simultanée des sels d'halogénure.
Orsten Stefan
Vandenmersch Hugues
Voss Hartwig
Wulff Christian
Basf Aktiengesellschaft
Robic
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