Method for reducing an .alpha.,.beta.-unsaturated ketone

Details Method for reducing an .alpha.,.beta.-unsaturated ketone Method for reducing an .alpha.,.beta.-unsaturated ketone

C - Chemistry, Metallurgy

07

D

C07D 307/935 (2006.01) C07B 31/00 (2006.01) C07C 1/207 (2006.01) C07C 67/297 (2006.01) C07C 69/76 (2006.01) C07D 333/78 (2006.01) C07D 493/04 (2006.01)

Patent

CA 2111820

A method for reducing an .alpha.,.beta.-unsaturated ketone of the present invention includes the step of treating the .alpha.,.beta.-unsaturated ketone with a silyl compound in the presence of a Lewis acid and alcohol to selectively reduce the carbonyl group of the .alpha.,.beta.-unsaturated ketone. According to this method, a deoxy-compound can be obtained from the .alpha.,.beta.-unsaturated ketone by selectively reducing the carbonyl group without reducing an .alpha.,.beta.-unsaturated bond.

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