Method for reprocessing waste acid resulting from tio2...

C - Chemistry – Metallurgy – 01 – G

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C01G 49/08 (2006.01) C01C 1/02 (2006.01) C01F 11/46 (2006.01) C01G 49/06 (2006.01) C04B 11/26 (2006.01)

Patent

CA 2324527

The invention relates to a method for producing gypsum and an iron oxide pigment from the waste acid resulting from the production of titanium dioxide according to the sulfate process. The invention is characterized in that in an initial step the waste acid is partially neutralized using a calcium compound, resulting in the precipitation and possibly direct separation of gypsum. The remaining solution is neutralized further in a second step, with precipitation of a precipitate containing Ti, Al, Cr, V and possibly Fe(III). From the iron sulfate-containing solution obtained after separation of the solid, an iron oxide pigment is produced in a third step by addition of alkaline compounds and possibly ammonia and an oxidizing agent. By adding CaO and/or Ca(OH)2 ammonia is released from the (NH4)2SO4-containing solution obtained after separation of the iron oxide pigment.

L'invention concerne un procédé de production de gypse et d'un pigment d'oxyde de fer à partir de l'acide usé obtenu lors de la production d'oxyde de titane d'après le procédé au sulfate. Le procédé consiste, dans un premier temps, à neutraliser partiellement l'acide usé à l'aide d'un composé de calcium, ce qui donne une précipitation et éventuellement une séparation directe du gypse. Dans un deuxième temps, on continue à neutraliser la solution restante avec précipitation d'un précipité contenant du Ti, Al, Cr, V et éventuellement du Fe(III). Dans un troisième temps, un pigment d'oxyde de fer est produit à partir de la solution contenant du sulfate ferreux obtenue après séparation de la matière solide par addition de composés alcalins et éventuellement d'ammoniac et d'un agent d'oxydation. Par addition de CaO et/ou de Ca(OH)¿2?, la solution contenant (NH¿4?)¿2?SO¿4? obtenue après séparation du pigment d'oxyde de fer dégage de l'ammoniac.

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