Method for separating ammonia and water from mixtures,...

C - Chemistry – Metallurgy – 08 – J

Patent

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C08J 11/06 (2006.01) C01C 1/02 (2006.01) C02F 1/04 (2006.01) C08G 69/16 (2006.01) C08G 69/28 (2006.01) C08J 11/02 (2006.01)

Patent

CA 2565503

The invention relates to a method for the distillative separation of ammonia and water from mixtures arising during the production of polyamides, said mixture containing a lactam and/or diamines and, optionally, an aminonitrile and/or dinitrile in addition to cyclopentanones as foreign substances. Said method consists of two steps: 1) the mixture is distilled at 11 - 35 bars, resulting in the production of water, ammonia and cyclopentanone as overhead products (K1), and water, lactam and/or diamines and, optionally, aminonitrile and/or dinitrile, as base products (S1), and 2) K1 is distilled at 11 - 35 bars, resulting in the production of ammonia and cyclopentanone as an overhead product, and water as a base product (S2).

L'invention concerne un procédé de séparation distillative d'ammoniac et d'eau dans des mélanges produits lors de la fabrication de polyamides, contenant un lactame et/ou des diamines et éventuellement un aminonitrile et/ou dinitrile et cyclopentanone en tant qu'impureté. Ledit procédé comporte deux étapes: 1) distillation du mélange sous 11 à 35 bar de manière à obtenir de l'eau, de l'ammoniac et cyclopentanone en tant que produits de haut de colonne (K1), et de l'eau, le lactame et/ou les diamines et éventuellement l'aminonitrile et/ou le dinitrile en tant que produits de bas de colonne (S1); et 2) distillation de (K1) sous 11 à 35 bar de manière à obtenir de l'ammoniac et cyclopentanone en tant que produits de haut de colonne (K2), et de l'eau en tant que produit de bas de colonne (S2).

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