Method for sox removal by catalytic carbon

C - Chemistry – Metallurgy – 01 – B

Patent

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C01B 31/10 (2006.01) B01D 53/04 (2006.01) B01D 53/86 (2006.01) B01J 20/20 (2006.01) B01J 21/18 (2006.01) B01J 37/08 (2006.01)

Patent

CA 2132521

An improved process is provided for the removal of sulfur oxides from gas or liquid media containing oxygen and water by contacting said media with a catalytically-active carbonaceous char. The improvement is provided by the use of a catalytically- active carbonaceous char prepared by a low-temperature carbonization and oxidation of a bituminous coal or bituminous coal-like material followed by exposure to a nitrogen-containing compound during the initial high-temperature exposure of the low-temperature oxidized char. Following this initial high-temperature treatment the material can be further calcined or activated as desired.

L'invention concerne un procédé perfectionné d'extraction d'oxydes de soufre à partir de milieux gazeux ou liquides contenant de l'oxygène et de l'eau par mise en contact desdits milieux avec un produit de carbonisation carboné catalytiquement actif. Le perfectionnement consiste à utiliser un produit de carbonisation carboné catalytiquement actif préparé par carbonisation et oxydation à basse température de charbon bitumineux ou de matériau similaire au charbon bitumineux, et à exposer ce dernier à un composé contenant de l'azote pendant l'exposition initiale à haute température du produit de carbonisation oxydé à basse température. Après ce traitement initial à haute température le matériau peut être encore calciné ou activé si nécessaire.

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