Method for sulfonating acyloxybenzenes and neutralization of...

C - Chemistry – Metallurgy – 07 – C

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C07C 303/32 (2006.01) C07C 303/06 (2006.01) C07C 309/42 (2006.01) C07C 309/58 (2006.01) C11D 3/39 (2006.01)

Patent

CA 2063071

A method is provided for sulfonating an acyloxy substituted benzene ring to obtain high yields of desired sulfonated compounds that are useful as cleaning, bleaching, or fabric treating additives. A particularly preferred additive so prepared has the structure Image where R7 is a branched or unbranched alkyl with about 5 to 9 carbons and M is an alkali metal, an alkaline earth metal, or ammonium. The benzene ring is sulfonated by contacting with a molar excess of sulfur trioxide source and then irreversibly reacting the sulfur trioxide excess with a quenching agent. A neutralization process for preparing peracid precursors in high yield by neutralizing sulfonated aryl esters is also provided.

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