Method for the automatic electro-chemical determination of...

G - Physics – 01 – N

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324/27

G01N 31/16 (2006.01)

Patent

CA 1133060

ABSTRACT OF THE DISCLOSURE A method for the automatic, electro-chemical determination of the end point of titration utilizing an initial, continuous addition of the ti- trant, up to a predetermined value, followed by a step-by-step addition with a resting time inserted therebetween for stabilization of the solution is disclosed. As the titrant is being added to the bath sample in constant volume units, a measured value is formed after every such addition. The difference to the preceding measurement is determined and the three consec- utive differences of greatest magnitude are utilized in a mathematical for- mula for calculating the end point. The titration ceases when the greatest difference lies between two lesser values.

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