Method for the formation of a coating of metal oxides on an...

C - Chemistry – Metallurgy – 23 – C

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C23C 18/12 (2006.01) C25B 11/04 (2006.01)

Patent

CA 2520584

The invention relates to a method for the formation of a coating of metal oxides, with at least one precious metal of group VIII of the periodic table, optionally associated with titanium and/or zirconium on an electrically-conducting substrate made from steel or iron, comprising the application of a solution of acetylacetonates of said metal(s) dissolved in a solvent specifically solubilising each metal acetylacetonate, followed by drying and calcination of the coated substrate. The invention further relates to an activated cathode obtained from electrically-conducting substrates coated with metal oxides and use thereof for the electrolysis of alkaline metal chlorides.

L'invention concerne un procédé de formation d'un revêtement d'oxydes métalliques comprenant au moins un métal précieux du groupe VIII de la classification des éléments éventuellement associé à du titane et/ou du zirconium sur un substrat électroconducteur en acier ou en fer, qui consiste à appliquer une solution d'acétylacétonates dudit (desdits) métal (métaux) dissout(s) dans un (des) solvant(s) solubilisant spécifiquement chaque acétylacétonate métallique, puis à sécher et calciner le substrat revêtu. L'invention concerne également une cathode activée obtenue à partir du substrat électroconducteur revêtu d'oxydes métalliques et son utilisation pour l'électrolyse de solutions aqueuses de chlorures de métaux alcalins.

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