Method for the polymerization of vinyl chloride monomer in...

C - Chemistry – Metallurgy – 08 – F

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402/397, 23/431,

C08F 14/06 (2006.01) C08F 2/20 (2006.01)

Patent

CA 1261542

ABSTRACT OF THE DISCLOSURE The invention provides an improvement in the suspension polymerization of vinyl chloride in an aqueous medium in the presence of a monomer-soluble polymerization initiator, ac- cording to which the amount of polymer scale deposition on the reactor walls can be greatly decreased. The improvement comprises admixing the aqueous polymerization medium with (a) a water-soluble crosslinked copolymer of an unsaturated carboxylic acid monomer, e.g. acrylic acid, and a crosslink- ing monomer such as di(meth)allyl ether of diethyleneglycol and (b) a non-ionic surface active agent in combination.

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