Method for the preparation of alpha-chlorinated chloroformates

C - Chemistry – Metallurgy – 07 – C

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C07C 68/02 (2006.01)

Patent

CA 2278156

Novel catalysts for the synthesis of a alpha-chlorinated chloroformate from an aldehyde and phosgene are described. The catalysts include alkyl substituted guanidines, hexasubstituted guanidinium chlorides, substituted biguanidinium chloride, phenyldialkyliminiumtetraalkylguanidinium chloride, dialkylimidazolinium tetraalkylguanidinium chloride, phenyltetraalkylamidinium chloride and N,N-dialkyl-N'-alkylpyrrolidinium chloride.

L'invention concerne des catalyseurs conçus pour la synthèse d'un chloroformiate alpha-chloré à partir d'un aldéhyde et de phosgène. Ces catalyseurs renferment des guanidines à substitution alkyl, des chlorures de guanidinium hexa-substitués, du chlorure de biguanidinium substitué, du chlorure de phényldialkyliminiumtétraalkylguanidinium, du chlorure de dialkylimidazolinium tétraalkylguanidinium, du chlorure de phényltétraalkylamidinium, et du chlorure de N,N-dialkyl-N'-alkylpyrrolidinium.

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