Method for the production of precipitated calcium carbonate...

C - Chemistry – Metallurgy – 09 – C

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C09C 1/02 (2006.01) C01F 11/18 (2006.01)

Patent

CA 2478670

Disclosed is calcium carbonate with a high degree of brightness, which is produced by treating calcium carbonate, and/or the milk of lime used for the production thereof by reacting milk of lime with carbon dioxide, and/or at least one of the calcium-containing intermediate products used for the production of milk of lime, with a bleaching agent before, during, and/or following said reaction. Said bleaching agent contains at least one compound of formula A[(CR1R2)SOpM(1/q)]r (I), in which A represents NR3R4, NR3, N, or OH; R1, R2, R3, R4 independently represent hydrogen or an organic radical; M represents ammonium or a metal; p represents 2 or 3; q represents the valence of M; and r represents 1 if A=OH or NR3R4, 2 if A=NR3, and 3 if A=N. Said variables are independently selected for each individual compound and/or each [(CR1R2)SOpM(1/q)] group if a mixture of compounds is used and/or if r=2 or 3.

La présente invention concerne du carbonate de calcium à haut degré de blancheur qui est produit par traitement de carbonate de calcium et/ou du lait de chaux utilisé pour sa production par mise en réaction de lait de chaux avec du dioxyde de carbone et/ou d'au moins un des produits primaires contenant du calcium, utilisés pour la production du lait de chaux, avant et/ou après sa mise en réaction avec un agent de blanchiment qui contient un composé de formule (I) : A[(CR?1¿R?2¿)SO¿p?pM¿(1/q)?]¿r? (I), dans laquelle A représente NR?3¿R?4¿, NR?3¿, N ou OH; R?1¿, R?2¿, R?3¿, R?4¿ représentent indépendamment les uns des autres hydrogène ou un radical organique; M représente ammonium ou un métal; p représente 2 ou 3; q représente la valence de M; et r représente 1 pour A = OH ou NR?3¿R?4¿, 2 pour A = NR?3¿ et 3 pour A = N. Ces variables sont choisies indépendamment les unes des autres pour chaque composé individuel et/ou chaque groupe [(CR?1¿R?2¿)SO¿p?M¿(1/q)?] si on utilise un mélange de composés et/ou si r = 2 ou 3.

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