Method for the separation of intermediates which may be used...

C - Chemistry – Metallurgy – 07 – C

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C07C 253/34 (2006.01) C07C 253/30 (2006.01) C07C 255/59 (2006.01) C07D 307/87 (2006.01)

Patent

CA 2555980

The invention relates to a method of separating and isolating an acylated derivative of 4-[(S)-4-dimethylamino-1-(4-fluorophenyl)-1-hydroxybutyl]-3- hydroxymethylbenzonitrile by reaction of a mixture of the 4-[(S)-4- dimethylamino-1-(4-fluorophenyl)-1-hydroxy-butyl]-3-hydroxymethylbenzonitrile and an acylated derivative thereof with a compound which form a derivative of the 4-[(S)-4-dimethylamino-1-(4-fluorophenyl)-1-hydroxy-butyl]-3- hydroxymethylbenzonitrile containing a carboxylic acid group. The acylated derivative containing a carboxylic acid group precipitates once it is formed and may easily be separated from the reaction mixture.

L'invention concerne une technique de séparation et d'isolement d'un dérivé acylaté de of 4-[(S)-4-diméthylamino-1-(4-fluorophényl)-1-hydroxybutyl]-3-hydroxyméthylbenzonitrile par réaction d'un mélange de 4-[(S)-4-diméthylamino-1-(4-fluorophényl)-1-hydroxy-butyl]-3-hydroxyméthylbenzonitrile et d'un dérivé acylaté de cette substance avec un composé qui forme un dérivé de 4-[(S)-4-diméthylamino-1-(4-fluorophényl)-1-hydroxy-butyl]-3-hydroxyméthylbenzonitrile contenant un groupe acide carboxylique. Le dérivé acylaté contenant un groupe acide carboxylique précipite une fois formé et peut être séparé facilement du mélange de réaction.

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