Method for the synthesis of organic acid esters of...

C - Chemistry – Metallurgy – 07 – D

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C07D 307/46 (2006.01) C07D 307/50 (2006.01)

Patent

CA 2645060

Method for the manufacture of organic acid esters of 5-hydroxymethylfurfural by reacting a fructose or glucose-containing starting material with an organic acid or its anhydride in the presence of a catalytic or sub-stoechiometric amount of solid acid catalyst. The catalysts are heterogeneous and may be employed in a continuous flow fixed bed reactor. The esters can be applied as a fuel or fuel additive.

La présente invention concerne une méthode de fabrication d'esters d'acides organiques de 5-hydroxyméthylfurfural par mise en réaction d'un produit de départ contenant du fructose ou du glucose avec un acide organique ou son anhydride en présence d'une quantité catalytique ou sous-stAEchiométrique de catalyseur acide solide. Les catalyseurs sont hétérogènes et peuvent être employés dans un réacteur à lit fixe en flux continu. Les esters peuvent être employés en tant que carburants ou en tant qu'adjuvants de carburant.

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