Method of condensing and/or polymerising sulfonated lignin...

C - Chemistry – Metallurgy – 08 – H

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260/133

C08H 6/00 (2010.01)

Patent

CA 1095511

ABSTRACT OF THE DISCLOSURE: A method of condensing and/or polymerising sulfonated lignin containing materials to substantially water soluble products. The method comprises adjusting the pH of the material such that a 3 % aqueous solution of the material has a pH below 7, adjusting the moisture content of the pH adjusted material to a value from 1 to 15%, and subjecting the resulting material to a heat treatment at a temperature range from 80 to 225°C in a manner to maintain the moisture content of the material at a value sufficient to allow the conversion to proceed, but less than 15%, and for a time period sufficient to form products having a viscosity at least 25% higher than the viscosity of the starting material, the vis- cosities being measured in a 50% aqueous solution at room tem- perature. Polymers based on sulfonated lignins are thus produced in a substantially dry state and at relatively low temperature and the end products obtained exhibit remarkably increased viscosities.

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