Method of maintaining low values of cyanide in cyanate salt...

C - Chemistry – Metallurgy – 23 – C

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C23C 8/58 (2006.01) C23C 8/50 (2006.01) C23C 8/52 (2006.01)

Patent

CA 1049908

ABSTRACT OF THE DISCLOSURE: The invention relates to a method of maintaining at very low values the proportions of cyanides in molten-salt baths in which the main active principle is the cyanate anion CNO-, the method comprising the steps of conjointly providing in the salt bath sulphur in an amount between 0.001 and 0.1% of the weight of said bath, introducing periodically or conti- nuously into the bath at least one substrate comprising at least one carbonyl group =C =O in a quantity such that it corresponds to a weight of between 1 and 25 grams of CO per kg. of bath and per 24 hours maintenance at the bath working temperature of between 480° and 650°C. The substrate introducing the carbonyl group may also constitute a regenerating agent for the cyanate anion and can advantageously be obtained by baking carbamide for 3 to 10 hours at a temperature of between 150 and 450°C. The bath may be homogenized by agitation means including insufflation of air. The invention is especially applicable to the nitridation of mechanical parts in heat-treatment salt baths.

226907

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