Method of making a diastereomeric mixture containing two...

Details Method of making a diastereomeric mixture containing two... Method of making a diastereomeric mixture containing two...

C - Chemistry, Metallurgy

07

C

260/314, 260/316

C07C 227/18 (2006.01) C07C 229/02 (2006.01) C07C 323/52 (2006.01)

Patent

CA 1301768

84-P-0246 ABSTRACT In the process of hydrocarboxylating an .alpha.-enamide with CO and an organic hydroxyl compound to produce a N-acyl-.alpha.-amino acid ester the improvement comprising using as the organic hydroxyl compound reactant an organic hydroxyl compound which has a chiral center that is essentially all L or D thereby producing a reaction mixture having essentially no enantiomeric pairs and containing diastereomeric N-acyl-.alpha.-amino acid esters having two chiral centers. 341A

551674

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