Method of making diglyme soluble siloxane-imide copolymers

C - Chemistry – Metallurgy – 08 – G

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400/2005, 402/22

C08G 73/10 (2006.01) C08G 77/42 (2006.01) C08G 77/455 (2006.01) C08L 79/08 (2006.01)

Patent

CA 1262498

METHOD OF MAKING DIGLYME SOLUBLE SILOXANE-IMIDE COPOLYMERS Abstract There is provided a process for making diglyme soluble siloxane-imide copolymers consisting essentially of (a) heating a mixture of diglyme, azeotropic solvent, organic diamine and bis-aminoalkyl-terminated polydiorgano- siloxane to reflux and (b) adding to the refluxing mixture of (a) an organic dianhydride of the formula Image where Ar is an aromatic or aromatic containing group and Y is oxygen or sulfur. Block copolymers are obtained if the bis-aminoalkyl-terminated polydiorganosiloxane is not added to the reaction mass until after the reaction of the organic diamine and organic dianhydride has been completed.

492886

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