Method of manufacturing hydrogen peroxide

Details Method of manufacturing hydrogen peroxide Method of manufacturing hydrogen peroxide

C - Chemistry, Metallurgy

01

B

23/287

C01B 15/029 (2006.01)

Patent

CA 1137276

ABSTRACT A process for producing hydrogen peroxide wherein a gaseous mixture comprising hydrogen and oxygen is contacted with a catalyst in the presence of water and an organic solvent wherein: i) the organic solvent is immiscible with water and unreactive with hydrogen peroxide under the contacting cond- itions; ii) the distribution coefficient for hydrogen peroxide between the water and the organic solvent is greater than 1; iii) the catalyst is of the formula L2MX2 wherein L is a ligand represented by the formula A R1 R2 R3 wherein R1 R2 and R3 are alkyl, cycloalkyl or aryl groups, hydrogen or halogen, A is a Group 5b element selected from the group consisting of nitrogen, phosphorous and arsenic, M is a Group 8 metal and X is halogen, said catalyst being soluble in said organic solvent and insoluble In water; and iv) the gaseous mixture is non-ignitable under the process conditions characterized in that the organic solvent is selected from the group consisting of fluorocarbons, halofluorocarbons and mixtures thereof.

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