Method of preparing group 14 bridged biscyclopentadienyl...

C - Chemistry – Metallurgy – 07 – F

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Details

C07F 17/00 (2006.01) B01J 31/00 (2006.01) C07F 7/00 (2006.01) C07F 7/08 (2006.01) C07F 7/22 (2006.01) C07F 7/30 (2006.01) C08F 4/44 (2006.01) C08F 4/64 (2006.01) C08F 8/00 (2006.01) C08F 297/08 (2006.01) C08L 23/10 (2006.01) C08L 23/14 (2006.01) C07F 7/12 (2006.01)

Patent

CA 2398529

The present invention relates to ligands and the synthesis of those ligands for use in metallocene complexes. More particularly, the present invention relates to the synthesis of diarylsilyl bridged biscyclopentadienes using diarylsilyldisulfonates. Even more particularly, the present invention describes Group IV metallocenes containing diarylsilyl bridged bis- cyclopentadienyl ligands prepared from contacting a diarylsilyldisulfonate with an organometallic indenyl reagent.

La présente invention se rapporte à des ligands et à la synthèse de ces ligands qui sont destinés à être utilisés dans des complexes métallocènes. De manière plus particulière, la présente invention concerne la synthèse de bis-cyclopentadiènes à pont diarylsilyle effectuée à l'aide de diarylsilyldisulfonates. Plus particulièrement encore, l'invention porte sur des métallocènes du groupe IV contenant des ligands bis-cyclopentadiényle à pont diarylsilyle préparés au moyen de la mise en contact d'un diarylsilyldisulfonate avec un réactif indényle organométallique.

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