Method of preparing li1+xmn2-xo4 for use as secondary...

C - Chemistry – Metallurgy – 01 – G

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C01G 45/02 (2006.01) C01G 45/00 (2006.01) H01M 4/50 (2006.01)

Patent

CA 2207391

A continuous method of preparing a single phase lithiated manganese oxide intercalation compound of the formula Li1+x Mn2-x O4 comprising the steps of: mixing intimately a lithium hydroxide or a lithium salt and a manganese oxide or a manganese salt; feeding the intimately mixed salts to a reactor; continuously agitating the mixed salts in the reactor; heating the agitated mixed salts in the reactor at a temperature of from about 650°C to about 800°C for a time not in excess of about 4 hours in an oxygen-containing atmosphere; and cooling the reacted product to less than about 200°C in an oxygen- containing atmosphere for a time not in excess of about 2 hours.

Procédé de préparation en continu d'un composé d'insertion à l'oxyde de manganèse lithié à une seule phase de formule Li1+xMn2-xO4 comprenant les étapes suivantes: on mélange intimement un hydroxyde de lithium ou un sel de lithium et un oxyde de manganèse ou un sel de manganèse; on envoie dans un réacteur les sels intimement mélangés; on agite continuellement les sels mélangés dans le réacteur; on chauffe les sels mélangés agités dans le réacteur à une température comprise entre environ 650 DEG C et environ 800 DEG C pendant une durée ne dépassant pas quatre heures environ dans une atmosphère contenant de l'oxygène; et on refroidit le produit qui a réagi à environ 200 DEG C dans une atmosphère contenant de l'oxygène pendant une durée ne dépassant pas deux heures environ.

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