Method of preparing olefinic double bonds by splitting off...

C - Chemistry – Metallurgy – 07 – C

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204/91.03

C07C 17/25 (2006.01) B01J 19/08 (2006.01) B01J 19/12 (2006.01)

Patent

CA 1143328

ABSTRACT OF THE DISCLOSURE Compounds having an olefinic double bond are produced by splitting off hydrogen halide from the corres- ponding saturated compound containing hydrogen and halogen by irradiating the saturated compound, while in a gaseous state, with pulsed light under temperature and pressure conditions effective to produce a capture cross-section of from 10-15 to 10-25 cm2/molecule; in this manner vinyl chloride can be produced from dichlorethane; such olefinic double bond containing compounds can be produced efficiently at comparatively low temperatures and cost.

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