Method of preparing organosiloxanes and methylchloride

Details Method of preparing organosiloxanes and methylchloride Method of preparing organosiloxanes and methylchloride

C - Chemistry, Metallurgy

07

F

260/659, 260/445

C07F 7/08 (2006.01) C07C 17/16 (2006.01)

Patent

CA 1149405

Abstract of the Disclosure Organochlorosilanes are reacted with methanol in contact with a tetraorganophosphonium chloride catalyst to form organosiloxanes and methylchloride. The method avoids significant silicon-carbon bond cleavage and provides good conversion of the chlorine of the chlorosilane to methylchloride while avoiding undesirable dimethylether formation.

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