Method of preparing stable condensation products using a...

C - Chemistry – Metallurgy – 07 – F

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403/18, 260/457.

C07F 9/09 (2006.01) C07F 9/40 (2006.01) C08G 65/26 (2006.01) C08G 79/04 (2006.01)

Patent

CA 1050039

METHOD OF PREPARING STABLE CONDENSATION PRODUCTS USING A LEWIS ACID CATALYST Abstract of the Disclosure The neutralization of products which are phosphorus containing oligomers having Image linkages between phosphorus atoms and which are obtained by the self-condensation of .beta.-halo- alkyl esters of pentavalent phosphorus acids or by the condensa- tion of these esters with an alkyl ester of a pentavalent phos- phorus acid is accomplished by reaction with an alkylene oxide, either alone or in combination with water or an alcohol having the formula ROH where R is a C1-C20 alkyl group, and is enhanced by heating the products with a Lewis acid to promote alcoholysis reactions between labile groups contained therein and structures formed by alkylene oxide neutralization of free acid groups. The stabilized product formed by this process gives a better cure when incorporated in a polyurethane foam.

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