Method of producing chlorine dioxide

C - Chemistry – Metallurgy – 01 – B

Patent

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C01B 11/02 (2006.01) D21C 11/04 (2006.01)

Patent

CA 2178044

The invention relates to a process of producing chlorine dioxide comprising the steps of reducing chlorate ions in an acid reaction medium maintained in a reaction zone of a chlorine dioxide generator, which reaction medium contains alkali metal ions and sulfate ions, so to form chlorine dioxide and a solid salt of acidic alkali metal sulfate. The process further comprises the steps of separating said solid acidic alkali metal sulfate from the reaction medium, contact- ing said solid acldic alkali metal sulfate with an aqueous medium in a mixing tank to effect at least partial conversion to neutral solid alkali metal sulfate, separating the at least partially neutralized solid alkali metal sulfate from the aqueous medium on a rotary drum filter operating with vacuum inside and with part of the drum submerged in a slurry of the at least partially neutralized solid alkali metal sulfate and the aqueous medium, and forming an acid filtrate.

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