Method of producing hydroxyl radicals for chemical reactions

C - Chemistry – Metallurgy – 25 – B

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C25B 3/02 (2006.01) C07B 60/00 (2011.01) C02F 1/46 (2006.01) C07C 37/60 (2006.01)

Patent

CA 2383513

A method of reacting chemicals comprising the exposure of the reactants to ultrasound and electrochemical energies in the presence of a metal or metal salt and hydrogen peroxide. HO. radicals are efficiently formed and react with a carbon-based reactant to form a carbon radical which then reacts with other reactants or may dimerize. The invention regenerates the metal ions and may be performed using no special facilities. Increased product yield was achieved for a number of hydroxylation reactions.

Cette invention se rapporte à un procédé utilisé pour faire réagir des produits chimiques. En l'occurrence, on soumet à des ultrasons et à des énergies de nature électrochimiques les produits à faire réagir, en présence d'un métal ou d'un sel de métal et du peroxyde d'hydrogène. Les radicaux HO?.¿ qui se forment de façon puissante, viennent réagir avec un réactant carboné de façon à former un radical carboné qui vient à son tour réagir avec d'autres réactants ou vient éventuellement se dimériser. Cette invention, qui permet la régénération des ions métalliques, ne nécessite pour sa mise en oeuvre aucune installation spéciale. L'invention permet une production accrue de produit à l'occasion de plusieurs réactions d'hydroxylation.

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