Method of reprocessing zinc- and lead-containing residues...

C - Chemistry – Metallurgy – 22 – B

Patent

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53/28, 53/321, 5

C22B 19/30 (2006.01) C22B 5/16 (2006.01) C22B 7/00 (2006.01) C22B 7/02 (2006.01) C22B 13/02 (2006.01) C22B 19/04 (2006.01) C22B 19/34 (2006.01)

Patent

CA 2032759

Zinc- and lead-containing residues from metallurgical plants are reprocessed by a thermal treatment in a circulating fluidized bed system. A major part of the heat demand is satisfied by a com- bustion of solid carbon in the fluidized bed reactor of the circulating fluidized bed system. A reducing fluidizing gas, which is virtually free of free oxygen, is fed to the lower part of the fluidized bed reactor, A solid carbon content from 5 to 30 % is adjusted in the fluidized bed in the lower portion of the fluid- ized bed reactor, which is supplied in its upper por- tion with oxygen-containing gases and in which CO2 is formed only at such a rate that zinc metal is not reoxidized. Substantially all solids are removed in a recycling cyclone from the suspension which bas been discharged and are recycled. The gas is cooled to a temperature at which zinc metal is oxidized to ZnO. The dustlike zinc compounds and lead compounds are removed from the gas,

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