Method of sulfur purification

C - Chemistry – Metallurgy – 01 – B

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C01B 17/02 (2006.01) B01D 15/00 (2006.01) C22B 43/00 (2006.01)

Patent

CA 2091033

Metal impurities such as mercury, copper, lead, zinc, iron and cadmium that are contained in trace amounts in sulfur that has been recovered from zinc concentrates by direct pressure leaching or other hydrometallurgical processes can be removed effectively by bringing the molten sulfur, as it is held at a temperature not lower than the melting point of sulfur, into contact with activated alumina by passage through a packed layer of activated alumina or a filter coated with activated alumina, or by mixing with activated alumina under stirring or by passage through a fluidized layer of activated alumina. The method is capable of reducing the sum of metal impurities in the sulfur to 50 ppm or below, with the mercury content being 1 ppm or less, whereby sulfur having a purity of at least 99.99% that is advantageous for use as a raw material in the production of sulfuric acid and in other industries is manufactured at low cost on simple equipment.

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