Method of winning aluminum metal from aluminous ore

C - Chemistry – Metallurgy – 25 – C

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53/236, 204/49

C25C 3/24 (2006.01) C01F 7/70 (2006.01) C22B 21/00 (2006.01) C25C 3/06 (2006.01)

Patent

CA 1143694

ABSTRACT OF THE DISCLOSURE Aluminous ore such as bauxite containing alumina is blended with coke or other suitable form of carbon and reacted with sulfur gas at an elevated temperature. For handling, the ore and coke can be extruded into conveniently sized pellets. The reaction with sulfur gas produces molten aluminum sulfide which is separated from residual solid reactants and impurities. The aluminum sulfide is further increased in temperature to cause its decomposition or sublimation, yielding aluminum sub- sulfide liquid (AlS) and sulfur gas that is recycled. The aluminum monosulfide is then cooled to below its disproportion- ation temperature to again form molten aluminum sulfide and aluminum metal. A liquid-liquid or liquid-solid separation, depending on the separation temperature, provides product aluminum and aluminum sulfide for recycle to the disproportion- ation step.

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