Methods for the electrosynthesis of polyols

C - Chemistry – Metallurgy – 25 – B

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C25B 3/04 (2006.01) C25B 3/10 (2006.01)

Patent

CA 1270461

IMPROVED METHODS FOR THE ELECTROSYNTHESIS OF POLYOLS ABSTRACT OF THE DISCLOSURE The electrosynthesis of ethylene glycol conducted with a formaldehyde-containing electrolyte provides unexpectedly higher current efficiencies at pH's maintained above about 5 to below about 7. Performance may be improved further through use of electrolytes having high formaldehyde-low methanol concentrations and with oxygen-containing organic compounds. Cell components such as gas diffusion electrodes and oxidized carbon or graphite cathodes also enhance current efficiencies.

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