Microbicidal compositions and methods using combinations of...

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A01N 43/84 (2006.01) A01N 43/653 (2006.01) A01P 1/00 (2006.01) A01P 3/00 (2006.01)

Patent

CA 2378275

A method for increasing the effectiveness of the microbicide propiconazole, (see above formula) (RS)-1-2-[(2,4-dichlorophenyl)-2-propyl-1,3-dioxalan- 2ylmethyl]-1H-1,2,4-triazole, is described. In the method, propiconazole and a potentiator, an N-alkyl heterocyclic compound, its salt, or a mixture thereof, are applied to a substrate or aqueous system subject to the growth of microorganisms. The N-alkyl heterocyclic compound, its salt, or a mixture thereof is applied in an amount effective to increase the microbicidal activity of the microbicide. The N-alkyl heterocyclic compound has formula (I). The variable "n" ranges from 5 to 17, and the heterocyclic ring defined by (II) is a substituted or unsubstituted ring having four to eight members. Microbicidal compositions are described where propiconazole and an N-alkyl heterocyclic compound, its salt, or a mixture thereof are present in a combined amount effective to control the growth of at least one microorganism. Methods for controlling the growth of microorganisms on various substrates and in various aqueous systems are also described. The combination of propiconazole and N-alkyl heterocyclic compound, its salt, or a mixture thereof is particularly useful as microbicidal in the leather industry, the lumber industry, the papermaking industry, the textile industry, the agricultural industry, and the coating industry, as well as in industrial process waters.

L'invention concerne un procédé permettant d'augmenter l'efficacité du microbiocide propiconazole, (RS)-1-2-[(2,4-dichlorophényl)-2-propyl-1,3-dioxalan-2ylméthyl]-1H-1,2,4-triazole. Selon ce procédé, on applique du propiconazole et un potentialisateur, un composé hétérocyclique N-alkyle, son sel, ou un mélange de ces produits sur un substrat ou un système aqueux dans lequel on fait croître des micro-organismes. Le composé hétérocyclique N-alkyle, son sel, ou un mélange de ceux-ci est appliqué en quantité efficace pour augmenter l'activité microbicide du microbiocide. Le composé hétérocyclique N-alkyle est représenté par la formule (I) où la variable "n" est comprise entre 5 et 17, et où le noyau hétérocyclique défini par (II) est un noyau substitué ou non substitué comprenant de quatre à huit chaînons. Les compositions microbicides selon l'invention comprennent du propiconazole, un composé hétérocyclique N-alkyle, son sel ou un mélange de ces produits à raison d'une quantité combinée efficace permettant de réguler la croissance d'un micro-organisme au moins. L'invention concerne également des procédés de régulation de la croissance de micro-organismes sur divers substrats et dans divers systèmes aqueux. La combinaison du propiconazole et du composé hétérocyclique N-alkyle, de son sel ou d'un mélange de ces produits est particulièrement utile comme agent microbicide dans l'industrie du cuir, l'industrie du revêtement, ainsi que dans les eaux industrielles.

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