Mixed basic metal oxide catalyst

Details Mixed basic metal oxide catalyst Mixed basic metal oxide catalyst

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B01J 23/02 (2006.01) B01J 23/00 (2006.01) B01J 23/06 (2006.01) B01J 23/10 (2006.01) B01J 23/12 (2006.01) C07C 2/84 (2006.01) C07C 5/32 (2006.01) C07C 5/333 (2006.01)

Patent

CA 1330981

ABSTRACT A mixed basic metal oxide catalyst having the formula: xA.yB.zC.qO wherein A is an alkali metal selected from lithium, sodium, potassium, rubidium and cesium; B is a cation which has an ionization state 1 greater than the ionization state of C; B is selected from scandium, yttrium, lanthanum, actinium, aluminum, boron and mixtures thereof when C is selected from beryllium, calcium, strontium, barium, radium, zinc, mercury and mixtures thereof and B is selected from titanium, zirconium, hafnium, silicon and mixtures thereof when C is selected from scandium, yttrium, lanthanum, actinium, aluminum, boron and mixtures thereof; x and y are in mole fractions of z such that when z=1 then x=0.002 to 0.25, and y=0.001 to 0.25; and q is a number necessary to maintain charge balance with O being oxygen. The catalyst is useful for oxidative coupling of methane and aliphatic and alicyclic hydrocarbon compounds with an aromatic compound to produce higher molecular weight hydrocarbons; and for dehydrogenating hydrocarbon compounds to produce unsaturated aliphatic and alicyclic chains.

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