Mixed ligand metal complexes of nitric oxide-nucleophile...

C - Chemistry – Metallurgy – 07 – F

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C07F 1/00 (2006.01) A61K 31/28 (2006.01) A61K 31/30 (2006.01) A61K 31/315 (2006.01) A61K 31/44 (2006.01) A61K 31/555 (2006.01) C07F 3/00 (2006.01) C07F 5/00 (2006.01) C07F 7/00 (2006.01) C07F 9/00 (2006.01) C07F 13/00 (2006.01) C07F 15/00 (2006.01) C07F 19/00 (2006.01)

Patent

CA 2132847

Mixed ligand metal complexes of nitric oxide-nucleophile adducts, useful as cardiovascular agents of the formula KA, wherein A is [(M)x'x(L)y(R1R2N-N2O2)2], and M is a pharmaceutically acceptable metal, or where x is at least two, M may be a mixture of two different pharmaceutically acceptable metals; L is a ligand, different from (R1R2N-N2O2), and is bound to at least one metal; R1 and R2 are each organic moieties and may be the same or different; x is an integer of from 1 to 10, inclusive; x' is the formal oxidation state of the metal M, and is an integer of from 1 to 6 inclusive; y is an integer of from 1 to 18; inclusive, and where y is at least two, L may be the same ligand or a mixture of different ligands. z is an integer of from 1 to 20, inclusive; provided that where M is copper, x is one, L is methanol and y is one, that at least one of R1 or R2 is not ethyl; and K is a pharmaceutically acceptable counterion present in the composition when the overall charge of A is not zero counterion K being present only in an amount to neutralize A. Methods of treating mammals with such compounds are provided. Pharmaceutical compositions containing such compounds are also provided.

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