Modification of crystalline propylene polymers

C - Chemistry – Metallurgy – 08 – F

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400/6581

C08F 8/50 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1314344

ABSTRACT OF THE DISCLOSURE A method for the modification of crystalline polymers of propylene is disclosed. A major portion of particles of the propylene polymer is admixed with a minor portion of particles of a composition of a normally solid second polyolefin and an organic peroxide. The second polyolefin, which is a homopolymer of hydrocarbon alpha-olefins having 4 carbon atoms or copolymer thereof with a minor amount of ethylene, has a shear viscosity that is not more than 30% of that of the propylene polymer. The organic peroxide has a half-life at 150°C of from 1-120 minutes. The admixture is mixed at a temperature above the melting point of the propylene polymer and second poly- olefin for a period of time that is at least four times the half life of the organic peroxide at the temperature of mixing. The resultant polymers exhibit improved processability while retaining useful physical properties, for example for injection moulding end-uses. DC-0199

544797

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