Modified catalysts for the solar reduction of water

Details Modified catalysts for the solar reduction of water Modified catalysts for the solar reduction of water

B - Operations, Transporting

01

J

252/91, 204/91.8

B01J 27/02 (2006.01) B01J 23/42 (2006.01) C01B 3/04 (2006.01) C01B 3/08 (2006.01)

Patent

CA 1174224

ABSTRACT OF THE DISCLOSURE A photochemical reaction system which produces hydrogen by seduction of hydronium ions using methylviologen or a related compound as an electron-transfer agent and a platinum electron-transfer catalyst, wherein the catalyst is modified with a water-soluble divalent sulphur compound, or a sulphur compound in which the sulphur is reducible to the divalent state, in an amount sufficient to inhibit hydrogenation side-reactions during the reduction process but not sufficient to significantly suppress the reduction of hydronium ion to hydrogen by the electron- transfer agent.

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