Modified pictet-spengler reaction and products prepared...

C - Chemistry – Metallurgy – 07 – D

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C07D 471/14 (2006.01) C07D 471/04 (2006.01)

Patent

CA 2492540

A method of introducing a second stereogenic center into a tetrahydro-.szlig.- carboline have two stereogenic centers using a modified Pictet-Spengler reaction is disclosed. The method provides a desired cis- or trans-isomer in high yield and purity, and in short processes times.

L'invention concerne un procédé pour introduire un second centre stéréogénique dans une tétrahydro-.szlig.-carboline, afin d'obtenir un composé présentant deux centres stéréogéniques au moyen d'une réaction de Pictet-Spengler. Ledit procédé permet d'obtenir rapidement un isomère cis ou trans voulu, avec un grand rendement et une pureté élevée.

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