Modified polymer particle, packing material and column for...

C - Chemistry – Metallurgy – 08 – F

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C08F 8/32 (2006.01)

Patent

CA 2499605

An object of the present invention is to prevent an isolation of carboxyl group caused by hydrolysis of ester bond, which occurs when a polymer particle containing an ester bond is used in the presence of a strongly acidic or strongly alkaline solution to thereby improve the acid Ealkali durability of the polymer particle.When a polymer particle containing an ester bond is treated with an acid or alkali hydrous solution and thereby an ester bond which is located and exposed on the surface of the particle and is readily hydrolyzed is previously hydrolyzed to isolate a carboxyl group and then the free carboxyl group is capped by amidation, to thereby dissolve the above problem.

La présente invention permet de prévenir l'isolation d'un groupe carboxyle provoquée par l'hydrolyse d'une liaison ester qui se produit lorsqu'une particule polymère contenant une liaison ester est utilisée en présence d'une solution fortement acide ou alcaline afin d'améliorer la durabilité de l'acide/l'alkali de la particule polymère. Lorsqu'une particule polymère, contenant une liaison ester, est traitée avec une solution hydrique acide ou alcaline et, par conséquent, une liaison ester, qui est localisée et exposée sur la surface de la particule et est facilement hydrolysée, est auparavant hydrolysée pour isoler un groupe carboxyle, le groupe carboxyle libre est alors coiffé par amidation, ce qui permet de résoudre le problème précité.

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