Molded or formed poly(arylene thioether-ketone) articles

C - Chemistry – Metallurgy – 08 – L

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402/33, 400/5403

C08L 81/02 (2006.01) B29C 55/00 (2006.01) C08G 75/02 (2006.01) C08J 5/18 (2006.01) C08L 101/00 (2006.01)

Patent

CA 1304876

- 59 - ABSTRACT Disclosed herein is a molded or formed poly(arylene thioether-ketone) article made of a thermoplastic material which comprises 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and if desired, up to 100 parts by weight of at least one of thermoplastic resins and/or up to 300 parts by weight of at least one of fibrous fillers and/or at least one of inorganic fillers. The PTK has predominant recurring units of the formula Image wherein the -CO- and -S- are in the para position to each other, and has a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, .DELTA.Hmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.2-2 d?/g as determined by viscosity measurement at 25°C and a polymer concentration of 0.5 g/d? in 98 percent by weight sulfuric acid. This invention provides extruded articles, injection-molded articles, unstretched films and the like, all of which have practical physical properties, by using a novel high-density and high-crystallinity PTK having melt stability sufficient to apply conventional melt processing techniques.

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