Molybdenum-based catalyst composition for polymerizing...

C - Chemistry – Metallurgy – 08 – F

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C08F 136/06 (2006.01) C08F 4/69 (2006.01)

Patent

CA 2375504

A catalyst composition that is the combination of or the reaction product of ingredients including a molybdenum-containing compound, a hydrogen phosphite, and an organoaluminum compound. This catalyst composition is useful for polymerizing conjugated dienes and is particularly useful for polymerizing 1,3- butadiene into syndiotactic 1,2-polybutadiene.

L'invention concerne une composition de catalyse qui est le résultat de la combinaison entre un produit réactionnel d'ingrédients comprenant un composé contenant un molybdène, un phosphite d'hydrogène et un composé d'organo-aluminum. Cette composition est utile pour la polymérisation de diènes conjuguées et se prête tout particulièrement à la polymérisation de 1,3-butadiène en 1,2-polybutadiène syndiotactique.

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