Molybdenum oxycarbonitride compositions and processes for...

Details Molybdenum oxycarbonitride compositions and processes for... Molybdenum oxycarbonitride compositions and processes for...

C - Chemistry, Metallurgy

01

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252/103, 23/221,

C01G 39/00 (2006.01) B01J 23/28 (2006.01) B01J 27/24 (2006.01) C01B 21/082 (2006.01) C01C 1/04 (2006.01) C07C 1/04 (2006.01) C07C 1/10 (2006.01)

Patent

CA 1164626

ABSTRACT OF THE DISCLOSURE Novel face-centered, cubic molybdenum oxycarbo- nitride catalyst and compositions are described together with a general method of synthesis. The compositions can be obtained by the relatively low temperature thermal decomposition of an amine molybdate and can be amorphous, poorly crystalline, or substantially crystalline, and can unexpectedly possess high surface areas in the region of about 130 m2/g and higher. The crystalline compositions have the general formula: MoOaCbNc, where a, b and c are non-zero decimal values and the sum: a b + c, is less than or equal to about one, as evidenced by X-ray diffraction and chemical analyses. The compo- sitions are useful as catalysts in producing hydrocarbons from the reaction of CO and H2, and CO and steam, and also in producing ammonia from the catalyzed reaction between N2 and H2.

390728

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