Mono, bis or tris(2,2'-substituted bipyridine) complexes of...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01) C07F 9/00 (2006.01) C07F 15/02 (2006.01) C12Q 1/00 (2006.01) H01L 51/30 (2006.01)

Patent

CA 2080834

Mono, bis and tris(substituted 2,2'-bipyridine) complexes of iron, ruthenium. osmium or vanadium are described wherein the bipyridine is substituted by at least one electron donor group. The donor group is a hydroxy, alkoxy, aryloxy group or a primary, secondary or tertiary amino group. Processes for the preparation of these complexes.

La présente invention concerne une nouvelle famille de complexes mono, bis ou tris (2,2'-bipyridine substituée) d'un métal choisi parmi le fer, le ruthénium, l'osmium ou le vanadium, la bipyridine étant substituée par au moins un groupe donneur d'électrons. Selon l'invention ce groupe donneur d'électrons est choisi parmi un groupe hydroxy, un groupe alkoxy, un groupe aryloxy ou un groupe amine primaire, secondaire ou tertiaire. L'invention concerne également les procédés de préparation de ces complexes.

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