Monomeric n-methyleneaminoacetonitrile

C - Chemistry – Metallurgy – 07 – C

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260/562

C07C 121/30 (1980.01)

Patent

CA 1134861

ABSTRACT OF THE DISCLOSURE The novel monomeric compound N-methyleneaminoacetoni- trile is produced by reacting glycinonitrile with form- aldehyde in the absence of ammonia. The process is con- veniently carried out by forming aqueous glycinonitrile in situ using known methods, removing any excess ammonia from the reaction medium and then introducing at least an equimolar amount of formaldehyde. The reaction is allowed to proceed substantially to completion. The novel product has a higher melting point than the pre- viously reported trimer.

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