Monovalent metal salts of dodecametal triaconta carbonyls

Details Monovalent metal salts of dodecametal triaconta carbonyls Monovalent metal salts of dodecametal triaconta carbonyls

C - Chemistry, Metallurgy

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C01G 55/00 (2006.01) B01J 31/20 (2006.01) C01G 1/04 (2006.01) C07C 29/157 (2006.01) C07C 29/158 (2006.01) C07C 31/00 (2006.01)

Patent

CA 1045338

MONOVALENT METAL SALTS OF DODECAMETAL TRIACONTA CARBONYLS ABSTRACT OF THE INVENTION This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula: M2 [TyT'12-y (CO)30] wherein M is a monovalent metal cation which is one of lithium, sodium, potassium, rubidium, cesium, francium, rhodium, copper, silver, gold, iridium, indium, thallium, and radium, T and T' are each different metals and each is one of cobalt, rhodium and iridium and y may have values from 1 to 11. These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol. S P E C I F I C A T I O N -1-

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