Multi-stage hydrodesulfurization of cracked naphtha streams...

C - Chemistry – Metallurgy – 10 – G

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C10G 45/04 (2006.01) B01J 23/882 (2006.01) B01J 35/00 (2006.01) B01J 35/10 (2006.01) C10G 65/04 (2006.01) B01J 21/04 (2006.01) B01J 23/85 (2006.01)

Patent

CA 2486670

A process for the selective hydrodesulfurization of naphtha streams containing a substantial amount of olefins and organically bound sulfur. The naphtha stream is selectively hydrodesulfurized by passing it through a first reaction zone containing a bed of a first hydrodesulfurization catalyst, then passing the resulting product stream through a second reaction zone containing a bed of a second hydrodesulfurization catalyst, which second hydrodesulfurization catalyst contains a lower level of catalytic metals than the first hydrodesulfurization catalyst.

L'invention concerne un procédé d'hydrodésulfurisation sélective de flux de naphte renfermant une quantité importante d'oléfines et de soufre à liaisons organiques. Le flux de naphte est hydrodésulfurisé de manière sélective par passage à travers une première zone de réaction renfermant un lit d'un premier catalyseur d'hydrodésulfurisation, puis par passage du flux de produit obtenu à travers une seconde zone de réaction renfermant un lit d'un second catalyseur d'hydrodésulfurisation, celui-ci renfermant un taux inférieur de métaux catalytiques par rapport au premier catalyseur d'hydrodésulfurisation.

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